发明名称 |
Ionically polymer-bound transition metal complex for photochemical conversion of light energy |
摘要 |
Novel catalyst for the photochemical conversion and storage of radiant energy through the conversion of strained cyclic non-conjugated carbon containing compounds to their corresponding conjugated forms comprises ionically bonding a transition metal complex having a square planar geometry and multiple sites of coordination with an anion-exchange resin. A method is provided for the preparation of the novel catalyst and comprises forming an acid salt derivative of the transition metal complex and mixing it together with an anion-exchange resin. A process wherein the novel catalyst is added to a strained cyclic non-conjugated carbon containing compound resulting in the release of heat energy through the conversion of the non-conjugated carbon containing compound to its conjugated form. A process and sealed container means wherein the non-conjugated carbon containing compound and the catalyst are in compartments and are separated until heat energy is required. The means of separation is then broken and the non-conjugated carbon containing compound is converted to the conjugated form with the release of heat energy. A process and apparatus wherein the conjugated carbon containing compound is exposed to radiant energy and is converted to the non-conjugated form. The non-conjugated form is then combined with the catalyst described hereinabove, converting the non-conjugated form to the conjugated form and resulting in the release of heat energy which is collected.
|
申请公布号 |
US4565799(A) |
申请公布日期 |
1986.01.21 |
申请号 |
US19840630097 |
申请日期 |
1984.07.12 |
申请人 |
THE STANDARD OIL COMPANY (OHIO) |
发明人 |
GIORDANO, JR., PAUL J.;SMIERCIAK, RICHARD C. |
分类号 |
B01J31/22;B01J19/12;B01J31/08;B01J31/16;B01J31/18;C07C5/31;C09K9/00;(IPC1-7):B01J31/08 |
主分类号 |
B01J31/22 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|