发明名称 Method of preparing high cis-1,4 diene polymers having good green strength and tack.
摘要 <p>Diene poiymers naving a hign content of cis-1,4 addition are prepared by polymerizing a 1,3-diene monomer in a hydrocarbon solvent in the presence of a catalyst composition comprising (a) a carboxylated metal oxy borate compound in which the metal is nickel or cobalt, (b) an organometallic compound of a metal of Groups I, II, and III of the Periodic System, and (c) one or more fluorine containing compounds selected from the group consisting of boron trifluoride complexes with ethers, alcohols or mixtures thereof; hydrogen fluoride; hydrogen fluoride complexes with ethers, alcohols, or mixtures thereof and mixtures of said compounds. &lt;??&gt;The resultant polymers exhibit good green strength and tack and are particularly suitable for use as tire rubbers. </p>
申请公布号 EP0166849(A1) 申请公布日期 1986.01.08
申请号 EP19850101180 申请日期 1985.02.05
申请人 THE FIRESTONE TIRE & RUBBER COMPANY 发明人 KANG, JUNG W.;HALL, JAMES E.
分类号 C08F4/00;C08F4/42;C08F4/60;C08F4/70;C08F36/04;C08F136/00;C08F136/04;C08F136/06;(IPC1-7):C08F36/04 主分类号 C08F4/00
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