发明名称 Process for synthesizing alpha , beta -ethylenically unsaturated products using a multicomponent acidic catalyst composition
摘要 A process for preparing a catalyst composition wherein a Metal Hydrocarboxide I, such as aluminum secbutoxide, a Metal Hydrocarboxide II, such as silicon ethoxide, an acidic phosphorus-oxygen composition, such as phosphoric acid, and water, are reacted in the presence of a liquid organic medium, such as acetone, to form a catalyst precursor composition, which is then calcined to form the catalyst, is disclosed. The catalyst is useful for condensing carboxylic acids or their ester with aldehydes or acetals to synthesize alpha , beta -ethylenically unsaturated acids or esters, such as methylmethacrylate.
申请公布号 US4560790(A) 申请公布日期 1985.12.24
申请号 US19830520909 申请日期 1983.08.08
申请人 EXXON RESEARCH & ENGINEERING CO. 发明人 RYU, JI-YONG
分类号 B01J27/16;B01J31/12;C07C51/353;(IPC1-7):C07C67/343;C07C45/74 主分类号 B01J27/16
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