发明名称 A PROCESS FOR THE PREPARATION OF CYCLOBUTENE-SUBSTITUTED AROMATIC HYDROCARBONS
摘要 Process for the preparation of an aromatic hydrocarbon with a cyclobutene ring fused to the aromatic hydrocarbon which comprises, dissolving an ortho-alkyl halomethyl aromatic hydrocarbon in an inert solvent and pyrolyzing the solution of ortho-alkyl halomethyl aromatic hydrocarbon in the inert solvent under conditions such that the ortho-alkyl and the halomethyl substituents form a cyclobutene ring thereby forming an aromatic hydrocarbon having a fused cyclobutene ring. The ortho-alkyl group has the structural formula (R')2-CH-, wherein R' is separately in each occurance hydrogen or a C1-20 alkyl. The aromatic hydrocarbons with a cyclobutene ring fused to the aromatic hydrocarbon are useful in the preparation of monomers, which are then useful in the preparation of high performance polymers.
申请公布号 WO8505355(A1) 申请公布日期 1985.12.05
申请号 WO1985US00939 申请日期 1985.05.20
申请人 THE DOW CHEMICAL COMPANY 发明人 SO, YING-HUNG
分类号 C07C43/21;C07B31/00;C07B37/10;C07C1/00;C07C1/26;C07C13/44;C07C17/00;C07C17/25;C07C25/18;C07C27/00;C07C37/00;C07C39/17;C07C41/00;C07C41/24;C07C51/00;C07C51/347;C07C63/34;C07C67/00;C07C67/28;C07C67/30;C07C69/035;C07C69/76;C07C201/00;C07C231/00;C07C231/12;C07C233/65;C07C253/00;(IPC1-7):C07C39/17;C07C51/09 主分类号 C07C43/21
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