Rubber compositions and articles thereof having improved metal adhesion and metal adhesion retention

摘要

Rubber compositions and metal-reinforced rubber ply members have improved metal adhesion and metal adhesion retention to brass and brass-plated metallic reinforcement. The improvement comprises admixing from about 0.5 to about 10.0 parts per hundred rubber (phr) of nickel molybdate, cobalt molybdate or a mixture thereof with a vulcanizable rubber composition prior to embedding the metallic reinforcement therein and curing. A method for improving the metal adhesion and metal adhesion retention between a vulcanizable rubber and brass or brass-plated metallic reinforcement includes the steps of dispersing from about 0.5 to about 10.0 phr of nickel molybdate, cobalt molybdate or a mixture thereof in a vulcanizable rubber composition prior to curing.