| 摘要 |
PURPOSE:To produce easily an org. high polymer conductor having excellent conductivity and uniformity by dissolving a polymer having a ferrocene nucleus together with a supporting electrolyte in an org. solvent and subjecting the same to electrochemical doping in which controlled potential anodic oxidation is effected. CONSTITUTION:A polymer having a ferrocene nucleus such as polyvinyl ferrocene is dissolved together with a supporting electrolyte such as tetra-n-butyl ammonium perchlorate or the like in an org. solvent such as dichloromethane or the like to prepare an electrolyte soln. A working electrode consisting of a ''NESA'' glass plate, platinum plate or the like and a counter electrode consisting of a nickel plate, etc. are inserted into the electrolyte and a constant voltage electrode reaction is effected in such a way that the working electrode is made positive. The film of the anodized conductive high polymer of dark blue poly(vinyl ferrocene), etc. is thus deposited on the surface of the working electrode.
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