发明名称 |
Hydroformylation of allyl alcohol. |
摘要 |
<p>The hydroformylation of allyl alcohol by reaction thereof with carbon monoxide and hydrogen in the presence of a rhodium carbonyl or rhodium carbonyl-forming catalyst exhibits high selectivity towards 2-hydroxytetrahydrofuran, and good catalyst stability, with easy separation of product from catalyst when a bi-solvent system is used. This solvent system comprises two mutually-immiscible solvents, a non-polar solvent (e.g. an aromatic hydrocarbon) in which the catalyst is soluble, and a polar solvent (e.g. an amide) to dissolve the 2-hydroxytetrahydrofuran. </p> |
申请公布号 |
EP0151515(A2) |
申请公布日期 |
1985.08.14 |
申请号 |
EP19850300220 |
申请日期 |
1985.01.11 |
申请人 |
TEXACO DEVELOPMENT CORPORATION |
发明人 |
LIN, JIANG-JEN;KNIFTON, JOHN FREDERICK |
分类号 |
B01J31/00;B01J31/20;B01J31/24;C07B61/00;C07D307/20 |
主分类号 |
B01J31/00 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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