Process for preparing 3,4'-Amino-Nitro-Diphenylether.

摘要

A process for preparing 3,4 min -amino-nitro-diphenylether in a heterogenous phase, according to the phase-transfer catalysis method, in which para-chloro-nitrobenzene is reacted with an alkali metal or alkaline-earth metal salt, preferably sodium or potassium, of meta-amino-phenol, preferably at a temperature ranging from 50 DEG C to 120 DEG C, in the presence of a phase-transfer catalyst, preferably (1) an onium salt, more preferably a quaternary alkylammonium salt QR4Y wherein Q is selected from N, P, As, Sb etc., R is an alkyl radical containing up to 20 carbon atoms and Y is Cl, Br, or I, or (2) a crown ether, in a two-phase system consisting of (a) an organic phase represented by the para-chloro-nitrobenzene, optionally in an organic solution, and (b) by the meta-amino-phenol in the form of an alkali metal or alkaline-earth metal salt in an aqueous solution which is substantially immiscible with the first phase. In this way, 3,4 min -amino-nitro-diphenylether is obtained, which is a particularly useful intermediate for preparing fibres.