发明名称 |
PROCESS FOR THE PREPARATION OF ARYLHYDROXYLAMINES |
摘要 |
A process for producing arylhydroxylamines in high yield with minimal formation of by-product arylamines. A charge mixture is prepared comprising a nitroaryl compound, a platinum catalyst, a base, a sulfur compound, and a solvent for the nitroaryl compound. The sulfur compound is one in which divalent sulfur is bonded to two other moieties or a compound reducible to such divalent sulfur compound under catalytic hydrogenation conditions. Hydrogen is introduced into the mixture while the mixture is agitated at a temperature in a range of 0-40 DEG C thereby reducing the nitro group of the nitroaryl compound to the hydroxylamine group. |
申请公布号 |
DE3360135(D1) |
申请公布日期 |
1985.05.30 |
申请号 |
DE19833360135 |
申请日期 |
1983.01.25 |
申请人 |
MALLINCKRODT, INC. |
发明人 |
CASKEY, DOUGLAS C.;CHAPMAN, DOUGLAS W. |
分类号 |
C07B61/00;B01J23/00;B01J23/42;B01J31/00;B01J31/28;C07B;C07C;C07C67/00;C07C239/00;C07C239/08;(IPC1-7):C07C83/02;C07C135/00;C07C147/14;C07C149/06;C07C149/12 |
主分类号 |
C07B61/00 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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