发明名称 |
PROCESS FOR PREPARING OXALIC ACID DIESTERS |
摘要 |
This invention relates to an improved process for preparing a diester of oxalic acid by the vapor (or gaseous) phase catalytic reaction of carbon monoxide with an ester of nitrous acid in the presence of a catalyst composed of a platimun-group metal or a salt thereof supported on a solid carrier which is alumina having a specific surface area of not more than 90 m2/g. According to this process, the diester of oxalic acid can be produced at a high space time yield (based on the platinum-group metal) and high selectivity with reduced formation of a carbonic acid diester and carbon dioxide as by-products. A further advantage of this process is that the amount of the platinum-group metal used can be decreased and it can be easily recovered. |
申请公布号 |
CA1187094(A) |
申请公布日期 |
1985.05.14 |
申请号 |
CA19820394729 |
申请日期 |
1982.01.22 |
申请人 |
UBE INDUSTRIES, LTD. |
发明人 |
MIYAZAKI, HARUHIKO;SHIOMI, YASUSHI;FUJITUS, SATORU;MASUNAGA, KATSURO;YANAGISAWA, HIROSHI |
分类号 |
C07C69/00;C07C69/36 |
主分类号 |
C07C69/00 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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