Improved process for forming thermally stable thermotropic liquid crystalline polyesters of predetermined chain length.

摘要

An improved polymerisation process is provided for the formation of a polyester which is capable of forming an anisotropic melt phase and which optionally may include amide linkages. An approximately 0.4 to 3 percent molar excess of aromatic dicarboxylic acid monomer (e.g. terephthalic acid) and/or an esterified derivative thereof is provided in the polymerisation zone during the polymerisation reaction. Such monomer imparts dicarboxyaryl units to the interior of the resulting polymer chains and causes the polymer chains to terminate in carboxylic acid end groups and/or an esterified derivative thereof wherein the polymer chains achieve a predetermined average chain lengththrough the depletion of other monomers present in the polymerisation zone. The resulting polyester unlike the usual product of the prior art is substantially incapable of additional chain growth upon subsequent heating and accordingly may be relied upon to maintain a substantially constant viscosity during melt processing regardless of the duration of heating.