Recovery of uranium from wet process phosphoric acid by liquid-solid ion exchange.

摘要

Recovery of uranium from crude wet process phosphoric acid (WPA) by cation exchange using as cation exchanger a resin comprising active amino phosphonic or hydroxy phosphonic groups linked to a matrix. The operational steps comprise reduction of uranium in the WPA to the tetravalent state, contacting the WPAwith the cation exchange resin to load the latter with tetravalent uranium, displacing Fe<Sup>+2</Sup> from the resin, washing the resin with aqueous ammonia, eluting the resin with a carbonate-bicarbonate solution and precipitating uranium from the eluate.