发明名称 |
Process for the hydroxylation of olefins using molecular oxygen, an osmium containing catalyst, a copper co-catalyst, and a cycloaliphatic amine based promoter |
摘要 |
A process directed to the hydroxylation of olefins by reacting said olefins in the presence of oxygen, water, and a catalyst composition comprising (i) a catalytically active osmium containing compound, (ii) a Co-catalyst I comprising a copper containing compound such as CuBr2, and (iii) a Co-catalyst II capable of increasing the rate and/or selectivity of the hydroxylation reaction, such as 1,4-diazabicyclo [2.2.2.] octane is disclosed.
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申请公布号 |
US4496779(A) |
申请公布日期 |
1985.01.29 |
申请号 |
US19840604043 |
申请日期 |
1984.04.26 |
申请人 |
EXXON RESEARCH & ENGINEERING CO. |
发明人 |
MYERS, RICHARD S.;MICHAELSON, ROBERT C.;AUSTIN, RICHARD G. |
分类号 |
C07B41/02;B01J27/02;B01J27/08;B01J31/26;B01J31/28;C07C29/04;C07C29/50;C07C45/35;(IPC1-7):C07C29/04;C07C31/18;C07C31/22;C07C31/42 |
主分类号 |
C07B41/02 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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