发明名称 PROCESS FOR THE PREPARATION OF ENAMINES OR IMINES
摘要 A process for the preparation of enamines or imines by isomerization of allylamine derivatives is described. Allylamine derivatives represented by formula (I): <IMAGE> (I) are isomerized using as a catalyst a rhodium complex represented by formula (IV): [Rh(olefin)L]+ X-(IV) to form enamines or imines represented by, respectively, formula (II) or formula (III): <IMAGE> (II) or <IMAGE> (III) All of the symbols in the above formulae are as described. These enamines or imines are useful intermediates for the preparation of a number of organic compounds.
申请公布号 DE3261287(D1) 申请公布日期 1985.01.03
申请号 DE19823261287 申请日期 1982.06.30
申请人 TAKASAGO PERFUMERY CO LTD 发明人 OTSUKA, SEINOSUKE;TANI, KAZUHIDE;YAMAGATA, TSUNEAKI;AKUTAGAWA, SUSUMU;KUMOBAYASHI, HIDENORI;YAGI, MISAO
分类号 C07D295/02;B01J31/00;C07B61/00;C07C45/51;C07C45/56;C07C67/00;C07C209/00;C07C209/68;C07C211/21;C07C211/25;C07C211/28;C07C211/35;C07C213/00;C07C213/08;C07C215/22;C07C241/00;C07C251/02;C07C251/04;C07D295/023;(IPC1-7):C07C85/24;C07C87/24 主分类号 C07D295/02
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