发明名称 PROCESS FOR PREPARATION OF ALPHA-AROMATIC GROUP SUBSTITUTED ALKANOIC ACID OR ESTERS THEREOF
摘要 A process for preparing an alpha-aromatic group substituted alkanoic acid or its ester of the general formula <CHEM> wherein Ar represents an aromatic group and R<1> represents a hydrogen atom or a saturated aliphatic group, or Ar and R<1> may form a condensed ring together with the carbon atom to which they are bonded; and R<2> represents a hydrogen atom, an alkyl group, or a hydroxyalkyl group, characterized in that an alpha-sulfonyloxyketone acetal of the general formula <CHEM> wherein R<3> and R<4>, independently from each other, represent an alkyl group. or taken together, represent an alkylene group; R<6> represents a substituted or unsubstituted alkyl group or an aromatic group; and Ar and R<1> are as defined above, is hydrolyred, or treated with an agent having affinity for oxygen; and novel intermediate compounds of the general formula (II) used in aforesaid process.
申请公布号 PH17798(A) 申请公布日期 1984.12.13
申请号 PH19810000261 申请日期 1981.09.10
申请人 SAGAMI CHEMICAL RESEARCH CENTER 发明人 GENICHI TSUCHIHASHI;SHUICHI MITAMURA;KOUJI KITAJIMA
分类号 C07C43/307;C07C43/315;C07C45/46;C07C45/63;C07C49/80;C07C51/00;C07C57/30;C07C59/64;C07C67/297;C07C67/333;C07C69/612;C07C309/63;C07D209/46;C07D303/48;C07D317/20;C07D317/24;C07D333/22;C07D333/24 主分类号 C07C43/307
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