发明名称 |
Process for the isomerization of cyclopropyl ketones to 2,3-dihydrofurans |
摘要 |
A process is provided wherein cyclopropyl ketones are readily isomerized to 2,3-dihydrofurans. The process involves the thermal rearrangement of 1,1-disubstituted-2-alkylcyclopropanes or 1,1-disubstituted-2-alkenylcyclopropanes, wherein one of the substituents in the 1-position is an acyl group, to 2,4,5-trisubstituted-2,3-dihydrofurans employing an onium compound as the catalyst.
|
申请公布号 |
US4487946(A) |
申请公布日期 |
1984.12.11 |
申请号 |
US19830503952 |
申请日期 |
1983.06.13 |
申请人 |
NATIONAL DISTILLERS AND CHEMICAL CORPORATION |
发明人 |
HALL, ALLEN L.;FAYTER, JR., RICHARD G. |
分类号 |
C07D307/30;C11B9/00;(IPC1-7):C07D307/28 |
主分类号 |
C07D307/30 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|