| 摘要 |
Process for the preparation of carbamates and/or derivatives thereof by reacting an organic compound containing at least one hydroxyl group with carbon monoxide and an organic nitrogeneous compound in the presence of a catalytic system based on palladium and a ligand according to the general formula: <IMAGE> (I) wherein L=N, P, As or Sb; R, R1, R2 and R3 are (un)substituted alkyl, aryl, alkaryl or aralkyl or R and R1 and/or R2 and R3 may form a ring together with the atom L to which they are attached; R4 and R5 are H or lower alkyl and n=2, 3 or 4, whereas carbon atoms between the groups L may be part of cyclic or non-cyclic unsaturated structures, and in the presence of an acid promoter.
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