发明名称 CYCLOHEXENONE DERIVATIVE, ITS PREPARATION AND SELECTIVE HERBICIDE
摘要 NEW MATERIAL:The compound of formula I [R1 is 1-6C acyl, lower alkylsulfonyl, lower alkoxycarbonyl, lower alkylaminocarbonyl (substituted) lower alkyl, etc.; R2 is lower alkyl; R3 is lower alkyl or lower alkenyl] and its metallic salt. EXAMPLE:2-[ 1-( Ethoxyimino )propyl ]-3-hydroxy-5-[ 4-(methanesulfonyloxy)- phenyl]-2-cyclohexen-1-one. USE:A selective herbicide exhibiting excellent effect especially by the foliar treatment compared with known compounds. PREPARATION:The compound of fomrula I can be prepared by reacting the compound of formula II with a hydroxylamine derivative of formula R3ONH2 in an inert solvent such as alcohol, optionally substituting the reaction solvent with other solvent after the reaction, extracting the reaction mixture with an alkali, acidifying the alkaline layer with hydrochloric acid, and separating the precipitated crystal of the objective compound.
申请公布号 JPS59163363(A) 申请公布日期 1984.09.14
申请号 JP19830037111 申请日期 1983.03.07
申请人 NIPPON SODA KK 发明人 IWATAKI ISAO;KAERIYAMA MINORU;ISHIKAWA HISAO;HOSAKA HIDEO;OBARA KENICHI;NAKAYAMA AKIRA
分类号 A01N47/06;A01N35/10;A01N41/04;A01N41/10;A01N47/22;C07C67/00;C07C239/00;C07C251/44;C07C301/00;C07C303/30;C07C309/65;C07C313/00;C07C317/18;C07C319/20;C07C323/12 主分类号 A01N47/06
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