发明名称 PREPARATION OF 2,2'-AZOBIS(2,4-DIMETHYLVALERONITRILE) HAVING IMPROVED SOLVENT SOLUBILITY
摘要 PURPOSE:The titled isomer mixture useful as a polymerization initiator, etc., having improved solvent solubility, by blending a low-melting isomer of 2,2'- azobis(2,4-dimethylvaleronitrile) with a high-melting isomer of 2,2'-azobis(2,4- dimethylvaleronitrile) in a specific ratio. CONSTITUTION:A mixture of 2,2'-azobis(2,4-dimethylvaleronitrile) (ADVN for short) isomers consisting of =70-<100wt% (preferably 98-76wt%) low-melting isomer of ADVN and <=about 30wt% (preferably 2-24wt%) high-melting isomer of ADVN, having more improved solvent solubility than the low-melting isomer of ADVN. Improved solvent solubility of the ADVN is especially advantageous in the use of a polymerization initiator, an amount of a solvent used to dissolve the ADVN is extremely a small amount, physical properties of prepared polymer are raised, and reduction in production cost and improvement in operation environment can be attained.
申请公布号 JPS59157063(A) 申请公布日期 1984.09.06
申请号 JP19830031240 申请日期 1983.02.26
申请人 WAKO JUNYAKU KOGYO KK 发明人 TANAKA MIKIAKI;MIYAGAWA TSUTOMU;TAKEUCHI HIDEO
分类号 C07C67/00;C07C253/00;C07C255/04;C07C255/65;C08F4/04;C08J9/06;C08J9/10 主分类号 C07C67/00
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