| 摘要 |
<p>1. Process for the preparation of silicon hydride compounds, in particular of silane (SiH4 ) from halogen silanes, characterized in that halogen silanes, in particular tetrachlorosilane, are reacted with magnesium hydride in a solvent in the absence of additional catalysts and/or activators, which magnesium hydride is obtained by reacting magnesium with hydrogen in the presence of a catalyst consisting of a halide of a metal of sub-Groups IV to VIII of the periodic System and of an organic magnesium compound or of a magnesium hydride and optionally in the presence of a polycyclic aromatic compound or af a tertiary amine and optionally in the presence of a magnesium halide MgX2 where X = Cl, Br, l.</p> |
