| 摘要 |
The invention relates to a process for the preparation of methanol by converting a lower hydrocarbon or mixture of lower hydrocarbons to a first gas mixture containing CO and H2 and converting this first gas mixture to methanol at elevated temperature and increased pressure in the presence of a suitable catalyst. In order to obtain low energy requirements this process is characterized in that said lower hydrocarbon or mixture of lower hydrocarbons is converted in a first reactor to said first gas mixture consisitng substantially of CO, CO2 and H2, by partial oxidation thereof with oxygen and optionally water, at a reactor outlet temperature of between 800 and 1500 DEG C and a pressure of between 40 and 150 bar, that said first gas mixture is supplied to a second reactor where it is converted to a second gas mixture containing methanol at a temperature of between 240 and 320 DEG C and a pressure of between 40 and 150 bar in the presence of a suitable catalyst, that a third gas mixture consisting of the non converted gaseous components is separated from said second gas mixture by cooling, that from this third gas mixture prior to recirculation to the reactor carbon dioxide is removed in an amount that the molal ratio H2(2CO + 3CO2) in the combined said first gas mixture and the depleted third gas mixture is at least 0.90, which combined mixture is to be supplied to said second reactor, that the crude methanol, obtained by said cooling of said second gas mixture is expanded to a lower pressure, and purified and that the energy released during said partial oxidation and the conversion of said combined gas mixture to said methanol containing third gas mixture is at least in part used for the generation of steam. |
