发明名称 Photopolymerisation process with two exposures of a single layer
摘要 A layer of a liquid composition containing a compound (A) having in the same molecule at least one (meth)acryloyl group and at least one bicyclo[2.2.1]hept-2-ene-6-yl unit is exposed to actinic radiation so that the layer solidifies due to photopolymerisation of (A) through the (meth)acryloyl group(s), remaining, however, photocrosslinkable. When desired, the solidified layer is exposed, as through a negative, to a substantially greater amount of actinic radiation, the parts so further exposed becoming more highly photocrosslinked through the bicyclo[2.2.1]hept-2-ene-6-yl unit(s) and hence insoluble. An image is produced which can be developed by means of suitable solvents. Examples of (A) include 3-(methacryloyloxy)-2-hydroxypropyl bicyclo[2.2.1]hept-2-ene-6-carboxylate and 2-(acryloyloxy)ethyl methyl-5-carboxybicyclo[2.2.1]hept-2-ene-6-carboxylate.
申请公布号 US4440850(A) 申请公布日期 1984.04.03
申请号 US19820397373 申请日期 1982.07.12
申请人 CIBA-GEIGY CORPORATION 发明人 PAUL, JOHN G.;STARK, BERNARD P.;LOSERT, EWALD
分类号 G03F7/26;C07D207/44;C07D207/452;C07D209/78;C07D493/08;C08F32/00;G03F7/027;G03F7/038;G03F7/38;(IPC1-7):G03C5/00 主分类号 G03F7/26
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