发明名称 |
METHOD OF MANUFACTURING HYDROGEN PEROXIDE |
摘要 |
A process for producing hydrogen peroxide wherein a gaseous mixture comprising hydrogen and oxygen is contacted with a catalyst in the presence of water and an organic solvent wherein: i) the organic solvent is immiscible with water and unreactive with hydrogen peroxide under the contacting conditions; ii) the distribution coefficient for hydrogen peroxide between the water and the organic solvent is greater than 1; iii) the catalyst is of the formula L2MX2 wherein L is a ligand represented by the formula A R1 R2 R3 wherein R1 R2 and R3 are alkyl, cycloalkyl or aryl groups, hydrogen or halogen, A is a Group 5b element selected from the group consisting of nitrogen, phosphorous and arsenic, M is a Group 8 metal and X is halogen, said catalyst being soluble in said organic solvent and insoluble in water; and iv) the gaseous mixture is non-ignitable under the process conditions characterized in that the organic solvent is selected from the group consisting of fluorocarbons, halofluorocarbons and mixtures thereof. |
申请公布号 |
DE3161307(D1) |
申请公布日期 |
1983.12.08 |
申请号 |
DE19813161307 |
申请日期 |
1981.04.21 |
申请人 |
AIR PRODUCTS AND CHEMICALS, INC. |
发明人 |
DYER, PAUL NIGEL;MOSELEY, FRED |
分类号 |
B01J31/00;C01B15/029;(IPC1-7):C01B15/02 |
主分类号 |
B01J31/00 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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