发明名称 MONONUCLEAR OR POLYNUCLEAR TRANSITION METAL COMPLEX HAVING PENTALENE LIGAND BOUND TO SINGLE METAL ATOM
摘要 PROBLEM TO BE SOLVED: To obtain the subject new complex compound comprising a transition metal complex containing at least one (substituted) pentalene ligand coordinated on only one single metal atom and useful for catalysts for polymerizing olefins, especially ethene, and so on. SOLUTION: A new complex compound having at least one transition metal atom, containing at least one (substituted) pentalene ligand coordinated on only one single metal atom and represented by formula I [M<1> is a metal atom belonging to the group III to the group IV; R<1> is H or methyl; X is a halogen, an alkyl, an aryl or H; Y is THF, an amine, a phosphane or CO; Z is cyclopentadienyl, indenyl or the like; (k) and (r) are each 0, 1 or 2: (m) is 0, 1, 2 or 3], formula II (R<2> is the same as R<1> ) or the like. The new complex compound is useful for olefin polymerization catalysts or the like. The compound is obtained by allowing a transition metal compound having a halogeno group and a (substituted) cyclopentadienyl or indenyl ligand to react with a (substituted) pentalene dianion capable of being replaced by the ligand.
申请公布号 JPH11152295(A) 申请公布日期 1999.06.08
申请号 JP19980228922 申请日期 1998.08.13
申请人 STUDIENGES KOHLE MBH 发明人 JONAS KLAUS;KOLB PETER;KOLLBACH GUIDO
分类号 C07F5/00;C07F9/00;C07F11/00;C07F17/00;C08F4/602;C08F4/619;C08F4/6192;C08F4/642;C08F4/643;C08F4/68;C08F4/69;C08F10/00;(IPC1-7):C07F17/00 主分类号 C07F5/00
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