发明名称 COSMETIC FILTER COMPOSITIONS CONTAINING DIBENZOYLMETHANE, ALKYL beta, beta<'>-DIPHENYLACRIAZOLE SILICONE AND USE THEREOF
摘要 1. Antisolar composition, characterized in that comprises three sun protection filters in a cosmetically-acceptable carrier, namely I) at least one dibenzoylmethane derivative, II) at least one alkyl-&beta;, &beta;'-diphenylacrylate derivative and III) at least one benzotriazole silicone responding to one of formulas (1) or (2): wherein -R, identical or different, are selected from the group comprising alkyl having 1-10 carbon atoms, phenyl, 3,3,3-trifluoropropyl and trimethylsilyloxy group, wherein, at least, 80% of total number of radical R are methyl; -B, identical or different, are selected from the group, comprising R and A; - r is an integer from 0 to 50 inclusively; - s is an integer from 0 to 20 inclusively, and if s =0, at least one two symbols B is A; - u is an integer from 0 to 10 inclusively, in case, that (t+U) is equal or exceeds 3; and symbol A is a monovalent radical, directly bound with a silicon atom and responding the following formula (3): wherein -Y, identical or different, are selected from a group, comprising alkyl, having 1-8 carbon atoms, halogen and alkoxy radical having 1-4 carbon atoms with the proviso that in the last case two Y, adjacent with one and the same aromatic core can form together a dioxyalkylidine group, in which alkylidine comprises 1-2 carbon atoms; - X is O or NM; - Z is hydrogen or alkyl radical having 1-4 carbon atoms; - m is 0 or 1; - p is an integer from 1 to 10 inclusively; as a third filter. 2. Composition of Claim 1, wherein dibenzoylmethane is selected from the group comprising: 2-methyldibenzoylmethane, 4- methyldibenzoylmethane, 4-isopropyldibenzoylmethane, 4-tret.-butyldibenzoylmetane, 2,4-dimethyldibenzoylmethane, 2,5-dimethyldibenzoylmethane, 4,4'-diisopropyldibenzoylmethane, 4-tert.-butyl-4'-methoxydibenzoylmethane, 2-methyl-5-isopropyl-4'-methoxydibenzoylmethane, 2-methyl-5-tert.-butyl-4'-methoxydibenzoylmethane, 2,4-dimethyl-4'methoxydibenzoylmethane, 2,6-dimethyl-4-tret.-butyl-4'-methoxydibenzoylmethane. 3. Composition of Claim 1, wherein dibenzoylmethane derivative is 4-tret.-butyl-4'-metoxydibenzoylmethane. 4. Composition of Claim 1, wherein dibenzoylmethane derivative is 4-isopropyldibenzoylmethane. 5. Composition of any Claim 1-4, wherein dibenzoylmethane derivative is present in composition in quantity from 0,1 to 8% by weight as per total mass of the composition. 6. Composition of Claim 5, wherein dibenzoylmethane derivative is present in composition in quantity from 0,2 to 5% by weight as per total mass of the composition. .7. Composition of any Claim 1-6, wherein alkyl-&beta;, &beta;'-diphenylacrylate derivative is selected from 2-ethylhexyl-&alpha;-cyano-&beta;, &beta;'-diphenylacrylate and ethyl &alpha;-cyano-&beta;, &beta;'-diphenylacrylate. 8. Composition of any Claim 1-6, wherein alkyl-&beta;, &beta;'-diphenylacrylate derivative is 2-ethylhexyl-&alpha;-cyano-&beta;,&beta;'-diphenylacrylate. 9. Composition of any Claim 1-8, wherein alkyl-&beta;, &beta;'-diphenylacrylate derivative is present in composition in quantity from 0.1 to 20% by weight as per total mass of the composition. 10. Composition of Claim 9, wherein alkyl-&beta;, &beta;'-diphenylacrylate derivative is present in composition in quantity from 0.1 to 20% by weight as per total mass of the composition. 11. Composition of any Claim 1-10, wherein benzotriazole is selected from compounds of general formula (1) in which radicals B are selected from radicals R. 12. Composition of Claim 11, wherein benzotriazole is selected from compounds having, at least, one the following characteristics: -R is alkyl and more preferably methyl; -r is an integer from 0 to 15 inclusively; -s is an integer from 1 to 10 inclusively; -n is not nil and preferably 1; and Y is selected from methyl, tret-butyl or alkoxy having 1-4 carbon atoms -Z is hydrogen of methyl; -m is 0 or (m=1 and X=0); -p is 1. 13. Composition of Claim 11, wherein benzotriazolesilicone presents in total characteristics, defined in Claim 12. 14. Composition of Claim 13, wherein benzotriazolesilicone is selected from compounds of general formula (4): wherein 0 <= r <= 10; 1 <= s <= 10; and wherein D is divalent radical 15. Composition of Claim 14, wherein benzotriazolesilicone responds the following formula: 16. Composition of any Claim 1-8, wherein benzotriazolesilicone is present in composition in quantity from 0.1 to 15% by weight as per total mass of the composition. 17. Composition of Claim 16, wherein benzotriazolesilicone is present in composition in quantity from 0.2 to 10% by weight as per total mass of the composition. 18. Method of cosmetic treatment for protection skin and/or hair against ultra-violate radiation, wherein it consists in applying an effective quantity of cosmetic composition, defined in any preceding Claim.
申请公布号 EA000577(B1) 申请公布日期 1999.12.29
申请号 EA19970000442 申请日期 1997.04.03
申请人 L'OREAL 发明人 ASCIONE, JEAN-MARC
分类号 A61K8/00;A61K8/31;A61K8/35;A61K8/37;A61K8/40;A61K8/49;A61K8/58;A61K8/896;A61K8/898;A61Q1/00;A61Q1/04;A61Q1/06;A61Q1/10;A61Q1/12;A61Q5/04;A61Q5/08;A61Q5/10;A61Q17/04;C08L83/08 主分类号 A61K8/00
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