发明名称 |
Process for extractively separating a mixture containing phosphoric acid monoalkylesters into its components |
摘要 |
The invention relates to a process for separating a mixture containing phosphoric acid monoalkylesters, phosphoric acid dialkylesters and minor proportions of diphosphoric acid dialkylesters, each with 6 to 12 carbon atoms in the alkyl radical, by extractively distributing them between an aliphatic or aromatic hydrocarbon as an unpolar solvent and a polar solvent. To this end, the invention provides: for the ester mixture to be admixed with the quantity of water stoichiometrically necessary for hydrolyzing the P-O-P-bond of the diphosphoric acid dialkylester with the resultant formation of the phosphoric acid monoalkylester; for the whole to be maintained for at least 1 hour at temperatures higher than 60 DEG C.; for the partially hydrolyzed ester mixture to be treated in a countercurrent apparatus comprising n-stages with the solvents immiscible or partially miscible with one another so as to ensure introduction of pure solvent into stage 1 and stage n, respectively, and the introduction of partially hydrolyzed mixture into one of the stages 2 to (n-1), n standing for a whole number of at least 3.
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申请公布号 |
US4410466(A) |
申请公布日期 |
1983.10.18 |
申请号 |
US19810327429 |
申请日期 |
1981.12.04 |
申请人 |
HOECHST AKTIENGESELLSCHAFT |
发明人 |
SCHIMMEL, GUENTHER R.;KLOSE, WERNER |
分类号 |
C07F9/02;C07F9/11;(IPC1-7):C07F9/09 |
主分类号 |
C07F9/02 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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