发明名称 |
Hydroformylation of olefinically unsaturated compounds |
摘要 |
A process for hydroformylating olefinically unsaturated compounds by means of rhodium/triphenylphosphine/carbonyl complexes formed in situ from rhodium acetate, triphenylphosphine and carbon monoxide, wherein the hydroformylation reaction is preceded by a starting phase in which the mixture of the hydroformylation medium, the triphenylphosphine and rhodium acetate is heated at from 90 DEG to 120 DEG C. under a CO/H2 pressure of from 5 to 20 bar and the acetic acid liberated is discharged from the reactor in gaseous form in a stream of CO and H2, until virtually no more acetic acid can be detected in this gaseous discharge. |
申请公布号 |
US4400549(A) |
申请公布日期 |
1983.08.23 |
申请号 |
US19810324277 |
申请日期 |
1981.11.23 |
申请人 |
BASF AKTIENGESELLSCHAFT |
发明人 |
RICHTER, WOLFGANG;KUMMER, RUDOLF;SCHWIRTEN, KURT |
分类号 |
C07C27/22;B01J31/00;B01J31/24;C07B61/00;C07C27/00;C07C29/158;C07C45/49;C07C45/50;C07C67/00;(IPC1-7):07C45/50 |
主分类号 |
C07C27/22 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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