发明名称 PRODUCTION OF TERTIARY OLEFIN
摘要 PURPOSE:In the presence of a novel silica-alumina catalyst, which has high reproducibility and long life and is prepared in low costs by calcining at a specific temperature, and of steam, the catalytic reaction of a tertiary ether is carried out to produce a high-purity olefin in high conversion and high selectivity. CONSTITUTION:In the production of a tertiary olefin such as isobutylene by the catalytic reaction of a tertiary ether such as methyl t-butyl ether or ethyl t- butyl ether, a silica-alimina that is prepared by calcining at 700-1,100 deg.C, preferably 750-1,000 deg.C is used as a catalyst and the reaction is carried out in the presence of steam.
申请公布号 JPS58121221(A) 申请公布日期 1983.07.19
申请号 JP19820004325 申请日期 1982.01.14
申请人 MITSUBISHI GAS KAGAKU KK 发明人 KIDA KOUICHI;KAWAI YOSHIO;TAMURA YUTAKA;SUZUKI YOSHIHARU
分类号 C07C1/20;B01J21/00;B01J21/12;C07B61/00;C07C1/00;C07C11/02;C07C67/00 主分类号 C07C1/20
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