发明名称 Process for the preparation of alpha-alkyl-3- or -4-difluoromethoxyphenylacetic acids
摘要 Compounds of the formula <IMAGE> are prepared by a) reacting the corresponding alpha -alkyl-m- or p-methoxyphenyl-acetonitrile with concentrated hydrobromic acid and b) reacting the resulting, corresponding alpha -alkyl-m- or p-hydroxyphenylacetic acid with chlorodifluoromethane in an alkaline dioxane/water mixture. In formula I, R2 denotes ethyl, n-propyl or isopropyl. The substituent of the formula HCF2O- is in the m or p position in relation to the alkanoic acid group. The compounds of the formula I are starting products for the preparation of their new m-phenoxybenzyl and alpha -cyano-m-phenoxybenzyl esters. These esters are suitable for controlling insects and mites.
申请公布号 CH636838(A5) 申请公布日期 1983.06.30
申请号 CH19820002164 申请日期 1982.04.07
申请人 AMERICAN CYANAMID CO. 发明人 GERALD BERKELHAMMER;VENKATARAMAN KAMESWARAN
分类号 A01N37/38;A01N47/02;C07C51/347;C07C59/64;(IPC1-7):C07C59/64 主分类号 A01N37/38
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