发明名称 |
PROCESS FOR PREPARING AROMATIC CARBOXYLIC ACIDS |
摘要 |
<p>The invention relates to a process for preparing aromatic carboxylic acids by oxidation of an alkyl-aromatic hydrocarbon in the liquid phase in the absence of an aliphatic carboxylic acid, by means of a gas containing molecular oxygen and in the presence of a catalyst consisting of a cobalt compound that is soluble in the reaction mixture. The process according to the invention is characterized by the fact that in addition to the cobalt compound a catalyst is used that consists of a zirconium and/or hafnium compound soluble in the reaction mixture. The use of zirconium and/or hafnium as a catalyst in addition to cobalt enables a higher reaction rate to be reached at the same temperature, or the reaction to be carried out at a lower temperature with the same reaction rate, with a considerably better selectivity for the desired aromatic carboxylic acid being obtained at the same reaction rate than if only cobalt is used under otherwise identical conditions.</p> |
申请公布号 |
CA1146588(A) |
申请公布日期 |
1983.05.17 |
申请号 |
CA19800359362 |
申请日期 |
1980.08.29 |
申请人 |
STAMICARBON B.V. |
发明人 |
JONGSMA, CORNELIS;LAUGS, WILHELMUS T.A.M. |
分类号 |
B01J31/00;C07B61/00;C07C51/00;C07C51/265;C07C67/00;(IPC1-7):C07C63/06 |
主分类号 |
B01J31/00 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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