发明名称 CYCLOHEXANOL DERIVATIVE OF CARBOXYLIC ACID HAVING OPTICALLY ACTIVE 2-METHYLBUTYLPHENYL GROUP
摘要 NEW MATERIAL:A cyclohexanol derivative of a carboxylic acid having S-(+)-4- (2'-methylbutylphenyl) group expressed by formulaI[(n) and (m) are 0 or 1; R is 1-10 C alkyl; * is asymmetric carbon]. EXAMPLE:trans-4-( trans-4'-Propylcyclohexyl )cyclohexyl S-(+)-4-( 2''-methylbutyl) biphenyl-4'-carboxylate. USE:A liquid crystal display element substance, having the helical molecular structure and optical activity, and stable to heat, light, air and water. PROCESS:S-(+)-4-(2''-Methylbutyl)biphenyl-4-carboxylic acid expressed buy formula II is converted into an acid chloride by the conventional method and then reacted with a trans-4-(trans-4'-alkylcyclohexyl)cyclohexanol expressed by formula III in the presence of pyridine to give the compound expressed by formulaI(n and m are 1).
申请公布号 JPS5855447(A) 申请公布日期 1983.04.01
申请号 JP19810151632 申请日期 1981.09.25
申请人 CHISSO KK 发明人 SUGIMORI SHIGERU;TSUJI MASAKAZU;KOJIMA TETSUHIKO
分类号 C07C69/76;C09K19/30;C09K19/54 主分类号 C07C69/76
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