发明名称 MENTHYL ESTERS, PROCESS FOR THEIR PREPARATION AND THEIR USE IN ENANTIOMER SEPARATION OF CHIRAL CARBOXYLIC ACIDS
摘要 A substantially pure compound selected from the group consisting of the d-menthyl esters of 1RS-cis-, 1RS-cis/trans-, 1R-cis-, 1S-cis-, 1R-trans- and 1S-trans-3-(2,2-dichloro- and dibromo-vinyl)-2,2-dimethylcyclopropanecarboxylic acid, the 1-menthyl esters of 1RS-cis-, 1RS-trans-, 1RS-cis/trans-, 1R-cis-, 1S-cis-, 1R-trans- and 1S-trans-3-(2,2-dibromo-vinyl)-2,2-dimethyl-cyclopropanecarboxylic acid and the 1-menthyl esters of 1R-trans- and 1S-trans-3-(2,2-dichloro-vinyl)-2,2-dimethyl-cyclopropanecarboxylic acid. The esters are produced by reacting enantiomers of the acids with d- or 1-menthol are selectively crystallizing.
申请公布号 DE3061774(D1) 申请公布日期 1983.03.03
申请号 DE19803061774 申请日期 1980.07.07
申请人 BAYER AG 发明人 NAUMANN, KLAUS, DR.;RAUCHSCHWALBE, RUDOLF, DR.
分类号 C07B57/00;A01N53/00;A01N53/10;C07B31/00;C07C51/00;C07C51/493;C07C61/16;C07C61/40;C07C67/00;C07C67/08;C07C67/14;C07C67/30;C07C69/743;C07C69/747 主分类号 C07B57/00
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