发明名称 |
PROCESS FOR THE PRODUCTION OF UNSATURATED ALCOHOLS |
摘要 |
Olefinically unsaturated alcohols (I) are prepared by selective hydrogenation of the corresponding carbonyl compounds (II) in the liquid phase with hydrogen, using an Ru, Rh, Os, Ir or Pt catalyst and carrying out the hydrogenation in the presence of from 5 to 40% by weight, based on (II), of a tertiary amine. The process is of particular importance for the selective hydrogenation of alpha , beta -unsaturated carbonyl compounds (IIa) and amongst these specifically for the hydrogenation of citral to geraniol and nerol. The preferred amine is trimethylamine. |
申请公布号 |
EP0024648(B1) |
申请公布日期 |
1983.01.26 |
申请号 |
EP19800104827 |
申请日期 |
1980.08.14 |
申请人 |
BASF AKTIENGESELLSCHAFT |
发明人 |
HORNER, MICHAEL, DR.;IRGANG, MATTHIAS, DR.;NISSEN, AXEL, DR. |
分类号 |
C07C29/136;B01J23/00;B01J23/40;B01J31/00;B01J31/02;C07B31/00;C07B41/02;C07B61/00;C07C27/00;C07C29/141;C07C29/145;C07C33/02;C07C33/03;C07C33/30;C07C67/00;(IPC1-7):07C29/136;01J23/40;07C33/025;07C33/02;07C29/14;07C33/03 |
主分类号 |
C07C29/136 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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