发明名称 VERFAHREN ZUR HERSTELLUNG VON AETHERVERBINDUNGEN DURCH KATALYTISCHE HYDROGENOLYSE
摘要 In a process for producing an ether compound by the catalytic hydrogenolysis of an acetal compound in the presence of a catalyst, the improvement wherein an acetal compound of the following formula (2) <IMAGE> (2) wherein R represents a hydrogen atom or a lower alkoxy group, Y represents an alkylene group having 2 to 12 carbon atoms, n represents a positive number of from 1 to 6, the two groups R(YO)n may, together with the carbon atom to which they are bonded, represent a 1,3-dioxolane ring, and R1 and R2, independently from each other, represent a hydrogen atom or a C1-C6 alkyl group, provided that at least one of R1 and R2 represents a hydrogen atom, is catalytically hydrogenolyzed in the presence of a palladium catalyst on a carbon carrier in the absence of an acid substance added, thereby to form an ether compound of the following formula (1) R(YO)nCHR1R2 (1) wherein R, R1, R2, Y and n are as defined.
申请公布号 DE3224033(A1) 申请公布日期 1983.01.05
申请号 DE19823224033 申请日期 1982.06.28
申请人 MITSUBISHI PETROCHEMICAL CO.,LTD. 发明人 AYUSAWA,TADASHI;AOKI,TADAMICHI;NOMURA,YUTAKA
分类号 B01J23/44;C07C29/10;C07C29/141;C07C41/28;(IPC1-7):07C43/10;07C43/13;07C41/01 主分类号 B01J23/44
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