| 摘要 |
<p>Azo dyes of the formula <IMAGE> and external salts thereof, wherein F is the residue of a monoazo or disazo compound in 1:1 metal complex form or of a trisazo, disazoazoxy or tetrakisazo compound in metal-free or 1:1 metal complex form, each X is independently -NR2-Q-NR3R4 or -NR2-Q-N(+)R5R6R7, wherein Q is linear or branched C2-6alkylene or -NH-CO-CH2-, R2 is hydrogen or C1-4alkyl, each of R3 and R4 is independently hydrogen; C1-6alkyl; C2-6alkyl monosubstituted by cyano or hydroxy in the 2-, 3-, 4-, 5- or 6-position; phenyl(C1-3alkyl); phenyl(C1-3alkyl) having, on the phenyl ring, 1, 2 or 3 substituents selected from chloro, C1-4alkyl and C1-4alkoxy; C5-6cycloalkyl or C5-6cycloalkyl substituted by 1, 2 or 3 C1-4alkyl groups or -NR3R4 is a saturated or unsaturated 5- or 6-membered heterocyclic ring containing, in addition to the nitrogen atom, no further or one further hetero atom, each of R5 and R6 is independently C1-6alkyl; C2-6alkyl monosubstituted by cyano or hydroxy in the 2-, 3-, 4-, 5- or 6-position; phenyl(C1-3alkyl); phenyl(C1-3alkyl) having, on the phenyl ring, 1, 2 or 3 substituents selected from chloro, C1-4alkyl and C1-4alkoxy; C5-6cycloalkyl or C5-6cycloalkyl substituted by 1, 2 or 3 C1-4alkyl groups, and R7 is C1-4alkyl or benzyl or <IMAGE> is a saturated or unsaturated 5- or 6-membered heterocyclic ring containing, in addition to the nitrogen atom, no further or one further hetero atom or -N(+)R5R6R7 is pyridinium or pyridinium substituted by 1 or 2 methyl groups, each Z1 is independently -CO-, -SO2- or <IMAGE> wherein R1 is hydrogen or C1-4alkyl, and Y is chloro, hydroxy, amino, an aliphatic, cycloaliphatic or aromatic amino group or a saturated heterocyclic amino group in which the nitrogen atom is part of the heterocyclic ring, each Z2 is independently <IMAGE> wherein R1 is hydrogen or C1-4alkyl, m is 1, 2 or 3, n is 0, 1, 2, 3 or 4, and p is 0, 1, 2, 3 or 4, with the proviso that n+2p>/=m+1, useful for dyeing and printing cotton, paper and leather.</p> |
