发明名称 PROCESS FOR PREPARING HIGH CIS 3-(2,2,2-TRICHLOROETHYL)-2,2-DIMETHYLCYCLOPROPANE-1-CARBOXYLATES
摘要 A process is described whereby esters of 3-(2,2,2-trichloroethyl) -2,2 - dimethylcyclopropane - 1 - carboxylic acid are prepared predominantly in their cis isomer form. The process comprises treating a 4,6,6,6-tetrachloro-3,3-dimethylhexanoate with an alkali metal tert-alkoxide under controlled conditions of temperature in the presence of a defined solvent-cosolvent mixture. The products of the process are intermediates in the production of pyrethroid insecticides.
申请公布号 DE2963657(D1) 申请公布日期 1982.11.04
申请号 DE19792963657 申请日期 1979.02.09
申请人 FMC CORPORATION 发明人 KONDO, KIYOSHI;NEGISHI, AKIRA;SUGIMOTO, KIKUO
分类号 C07C67/30;A01N;A01N53/00;B01J31/00;B01J31/02;C07C;C07C23/04;C07C61/04;C07C67/00;C07C67/317;C07C69/74;C07C253/00;C07C255/39;C07C313/00;C07C319/20;C07C323/12;C07C323/19;C07C323/62;C07D209/48;C07D209/49;C07D307/42;C07D307/45;C07D307/54;C07D317/48;C07D317/50;C07D317/54;C07D317/60;C07D319/16;C07D333/16;C07D333/24;C07D333/26;(IPC1-7):C07C69/74 主分类号 C07C67/30
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