摘要 |
A process, or procedure, for the start-up of reforming units, particularly those employing highly active sulfur-sensitive polymetallic, promoted noble metal containing catalysts. On start-up of a reforming unit, a sulfur-containing naphtha feed is fed at reforming conditions over a platinum-catalyst containing lead reactor of a series while bypassing subsequent reactors of the series, the product therefrom is separated into hydrogen-containing gas and C5+ liquid fractions, the hydrogen-containing gas fraction is desulfurized and dried and recycled to the platinum-catalyst containing lead reactor and, after sufficient hydrogen has been generated for operation of a Hydrofiner which is used to hydrodesulfurize the naphtha feed for the reformer, product from the platinum-catalyst containing lead reactor is fed to subsequent reactors of the series which contain the more sulfur-sensitive catalysts.
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