| 摘要 |
1346360 Alkylation catalysts INSTITUT FRANCAIS DU PETROLE DES CARBURANTS ET LUBRIFIANTS 22 Sept 1971 [30 Sept 1970] 44233/71 Heading B1E [Also in Division C5] Catalyst for use in the alkylation of an aromatic hydrocarbon by an olefin or alkyl halide consists of a mixture or reaction product of (a) at least one organoaluminium compound having the formula RAlX 2 wherein R is a univalent hydrocarbon radical which may contain from 1 to 20 carbon atoms and which may be an alkyl, cycloalkyl, aryl or aralkyl group, for example a methyl, ethyl, propyl or butyl group, and each X is a halogen atom, for example a chlorine or bromine atom, and (b) at least one aromatic compound containing at least one benzene ring substituted by at least two hydroxyl groups. The or each organoaluminium compound may be formed in situ from aluminium trichloride and at least one compound selected from compounds having the formulae R 2 AlCl and R 3 Al; the or each aromatic compound, which preferably contains from two to four hydroxyl groups and may contain at least one nuclear substituent selected from halogen atoms and univalent hydrocarbon radicals containing from 1 to 20 carbon atoms, may be a compound having the formula Y n C 6 H 4-n (OH) 2 wherein n is 0, 1, 2, 3 or 4 and the or each Y is a halogen atom or an alkyl, cycloalkyl or aryl group, for example a chlorine atom or a methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl or tert-butyl group with the proviso that, when n is 2, 3 or 4, the or any two Y groups and the carbon atoms to which they are attached together may represent a cycloalkyl or aryl group. Exemplified organoaluminium compounds are ethyl aluminium dichloride and dibromide, npropyl aluminium dichloride and dibromide, isopropyl aluminium dichloride and dibromide, n-butyl aluminium dichloride and dibromide and isobutyl aluminium dichloride and dibromide; exemplified aromatic compounds are pyrocatechol; chloro- and bromo-catechols, for example 4-chlorocatechol; resorcinol; chloro- and bromo-resorcinols, for example 4-chlororesorcinol; hydroquinone; chloro- and bromohydroquinones, for example tetrachlorohydroquinone; pyrogallol; hydroxyquinol; phloroglucinol; 3,4-dihydroxytoluene; 1,3-dihydroxynaphthalene; 1,3-dihydroxynaphthalene-5, 7-disulphonic acid; 2,3-dihydroxynaphthalene; 1,2-dihydroxyanthracene; 9,10-dihydroxyanthracene; 1, 2, 10-trihydroxyanthracene and 3, 4-dihydroxyphenanthrene. Examples relate to the preparation of catalyst from ethyl aluminium dichloride and pyrocatechol (Examples 2 and 11) or 4-chlorocatechol (Example 15) or resorcinol (Examples 4 to 6 and 24 to 27) or hydroquinone (Example 3) or tetrachlorohydroquinone (Examples 7 to 10 and 16) or hydroxyquinol (Example 17) or 3, 4-dihydroxytoluene (Example 14) or 1, 3-dihydroxynaphthalene-5, 7-disulphonic acid (Example 18) or 1, 2, 10-trihydroxyanthracene (Example 19) or 3, 4-dihydroxyphenanthrene (Example 20); ethyl aluminium dibromide and pyrocatechol (Example 21); n-propyl aluminium dichloride and pyrocatechol (Example 22); isopropylaluminium dibromide and gyrogallol (Example 12); nbutyl aluminium dichloride and 1,3-dihydroxynaphthalene (Example 13); and isobutyl aluminium dibromide and pyrocatechol (Example 23). |
