发明名称 Phosphomolybdic-acid catalysts, production thereof and their use in the oxidation of methacrolein to methacrylic acid.
摘要 <p>Compositions of the empirical formula: Mo&lt;Sub&gt;12&lt;/Sub&gt; Po.&lt;Sub&gt;1&lt;/Sub&gt;-&lt;Sub&gt;3&lt;/Sub&gt; M&lt;Sub&gt;0.1-3&lt;/Sub&gt; Cu&lt;Sub&gt;0.1-2&lt;/Sub&gt; V&lt;Sub&gt;0.1-2&lt;/Sub&gt; X&lt;Sub&gt;0.1-2&lt;/Sub&gt; Y&lt;Sub&gt;a&lt;/Sub&gt; O&lt;Sub&gt;b&lt;/Sub&gt; (1) where M is at least one of K, Rb and Cs; &lt;UnorderedLists id="ula01" listStyle="none"&gt;&lt;ListItem&gt;X is at least one of Ba, La, Ga, Al, Ag, Cd, Ti, TI, Hg, Pb and Zn;&lt;/ListItem&gt;&lt;ListItem&gt;Y is at least one of Fe, Co, Ni, Sr, Mn, In, Ta, Ge, S and Be when a &gt; 0;&lt;/ListItem&gt;&lt;ListItem&gt;a is a number of 0 to about 2; and&lt;/ListItem&gt;&lt;ListItem&gt;b is a number that satisifies the valence requirements of the other elements present,&lt;/ListItem&gt;&lt;/UnorderedLists&gt;are excellent catalysts for the oxidation of methacrolein to methacrylic acid.</p>
申请公布号 EP0051348(A1) 申请公布日期 1982.05.12
申请号 EP19810302863 申请日期 1981.06.25
申请人 THE STANDARD OIL COMPANY 发明人 SHAW, WILFRID GARSIDE;PAPARIZOS, CHRISTOS;KUCH, PHILIP LAWRENCE
分类号 C07C57/055;B01J23/76;B01J27/198;B01J27/199;C07B61/00;C07C51/00;C07C51/235;C07C51/25;C07C67/00;(IPC1-7):01J27/18;07C51/25;01J23/88;07C57/04 主分类号 C07C57/055
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