发明名称 PRPARATION OF BISPHENOL A
摘要 PURPOSE:To obtain the titled compound, by treating a raw phenol by a specific method to prevent the deterioration of a catalytic activity previously, and reacting the treated phenol with acetone in the presence of a sulfonic acid type cation exchange resin catalyst modified with a compound having a mercapto group. CONSTITUTION:Phenol is reacted with acetone in the presence of a catalyst consisting of a sulfonic acid type cation exchange resin modified wih a compound having a mercapto group, e.g. a mercaptoalkylamine, to prepare bisphenol A. In the process, the phenol to be used as a raw material to previously brought into contact with the sulfonic acid type cation exchange resin preferably at 50-100 deg.C for 0.2-10hr at a space velocity of 1-10hr<-1>. EFFECT:The catalytic life can be prolonged.
申请公布号 JPS5772927(A) 申请公布日期 1982.05.07
申请号 JP19800148826 申请日期 1980.10.23
申请人 MITSUBISHI KASEI KOGYO KK 发明人 MORI HAJIME;MASUYAMA TETSUO;FUJII KAZUHIRO;YOKOYAMA TOSHIHARU;OOBA KENJI;TSURUGA MASAHIRO
分类号 C07C37/20;B01J31/00;B01J31/10;C07B61/00;C07C27/00;C07C39/16;C07C67/00 主分类号 C07C37/20
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