发明名称 |
Oxidation of di- and trimethyl aromatic hydrocarbons having ortho-oriented methyl groups in liquid phthalic acid |
摘要 |
Catalytic liquid phase molecular oxygen oxidation of methyl-substituted aromatic hydrocarbons having two or more methyl-substituents on adjacent ring carbon atoms in acetic acid reaction medium have, in general, resulted in a substantial production of the desired ortho-oriented di-, tri-, and higher polycarboxylic substituted aromatic acids but also in the co-production of substantial amounts of oxygenated intermediates including methyl-substituted mono- and non-ortho polycarboxylic acids. Several theories have been proposed, including inherent auto-inhibiton, for such incomplete oxidations.
|
申请公布号 |
US4322549(A) |
申请公布日期 |
1982.03.30 |
申请号 |
US19780874127 |
申请日期 |
1978.02.01 |
申请人 |
STANDARD OIL COMPANY (INDIANA) |
发明人 |
KUHLMANN, GEORGE E.;BEMIS, ALAN G. |
分类号 |
C07C51/265;(IPC1-7):C07C51/16 |
主分类号 |
C07C51/265 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|