摘要 |
1319178 Methin dyes BAYER AG 17 Aug 1971 [17 Aug 1970] 38495/71 Heading C4P Methin dyes of formula (in which R 1 and R 4 are each halogen, C 1 -C 5 alkyl, cycloalkyl aralkyl, alkoxy, nitro, carbalkoxy, CN, acyl, acylamino, carboxylic acid amide, alkylanilide or alkylamide, sulphonic acid amide or alkylamide, or CF 3 ; R 2 is H, 1-5 C alkyl, cycloalkyl, aralkyl or aryl; R 3 is H or alkyl or is an alkylene radical joined to the ortho position of aryl ring B to form a 5- to 6- membered ring which is optionally alkyl substituted or fused with a further carbocyclic ring; R 5 and R 6 are each 1-5 C alkyl, aralkyl or cycloalkyl; a and b are each 0-3; A is an anion; rings B and D are optionally fused with carbocyclic rings; the aromatic carbocyclic rings of the dye optionally contain one or more non-ionic substituents; in that at least one R 1 and R 4 radical is aralkyl). The dyes are prepared by conventional condensation reactions. Many pairs of suitable reactants are given (including mixtures, compounds in which ring D is fused to a benzo or cyclohexene ring, and compounds in which R 3 and ring B complete a 3 - methyl - 2,3 - dihydroindole, hexahydrocarbazole, 1,2,3,4 - tetrahydroquinoline or 7-methoxy-1,2,3,4-tetrahydroquinoline ring). |