PREPARATION OF SODIUM ORTHOPHOSPHATE MIXTURES

摘要

PREPARATION OF SODIUM ORTHOPHOSPHATE MIXTURES A mixture of disodium and monosodium orthophosphate in a 2:1 mole ratio is prepared by sequentially reacting phosphoric acid with monohydrate process soda ash and caustic soda in a semi-solid reaction medium. Milled monohydrate process soda ash is contacted in less than stoichiometric proportions with phosphoric acid and the resultant orthophosphate containing reaction mixture is brought to a sodium to phosphorus mole ratio of about 1.67:1 by subsequent reaction with caustic soda. The final reaction product of mixed disodium and monosodium orthophosphate is suitable feedstock for conversion to sodium tripolyphosphate. C-5245