发明名称 PROCEDE DE PREPARATION DE DERIVES DE CYCLOPENTENONE PAR TRANSPOSITION D'UN FURANECARBINOL
摘要 A process is made available for the preparation of cyclopentenones of the general formula I <IMAGE> in which R<1> denotes a hydrogen atom or a lower alkyl or lower alkenyl radical and R<2> denotes a hydrogen atom or a lower alkyl, lower alkenyl, lower alkynyl, substituted or unsubstituted aryl, aryl-lower alkyl, thienyl or cycloalkyl radical. In this process, a furancarbinol of the general formula II <IMAGE> in which R<1> and R<2> have the abovementioned meaning, is subjected to rearrangement. The resulting hydroxycyclopentenone of the general formula III <IMAGE> in which R<1> and R<2> have the abovementioned meaning, is subjected to reductive dehydroxylation. The cyclopentenones of the general formula I can easily be prepared in this manner in high yields and at high purity.
申请公布号 FR2488885(A1) 申请公布日期 1982.02.26
申请号 FR19810011542 申请日期 1981.06.11
申请人 SUMITOMO CHEMICAL CY LTD 发明人 MASAYOSHI NINAI
分类号 C07C45/59;C07C45/66;C07C45/67;(IPC1-7):C07C49/59;C07D333/22 主分类号 C07C45/59
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