| 摘要 |
Methyl ketones are prepared in liquid phase by oxidizing terminal olefins of the formula R-CH=CH2, where R is a hydrocarbon radical. The oxidizing agent is hydrogen peroxide or an organic hydroperoxide, and the catalyst is a palladium catalyst of the formula Pd AA', (Lm) where A is fluoborate, acetate or trefrafluoroacetate A' is the same as A or is pi -allyl, m is 0 or 2, and L is a ligand selected from the amines, the phosphines, the arsines, the stibines and the amides.
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