发明名称 Process for the preparation of trans-2,2-dimethyl-3-(2,2-dichloroethenyl)cyclopropane-1-carboxylic acid and its esters
摘要 Compounds of the formula: <IMAGE> in which R denotes alkyl, are obtained from alkyl esters of the formula: <IMAGE> by treating them with a base at elevated temperature or by treating them with a base and reacting the resulting alkyl trans-2,2-dimethyl-3-(trichloroethyl)cyclopropane-1-carboxylate (IV) with bicycloamine or a Lewis acid. The esters can be hydrolysed to give carboxylic acids (IA), which are also obtained via the intermediates IV either directly, by hydrolysing them with simultaneous elimination of HCl, or in two steps by hydrolysing them to corresponding carboxylic acids and treating the latter with a base or with a Lewis acid. Certain esters of the formula I are insecticides. <IMAGE>
申请公布号 CH624920(A5) 申请公布日期 1981.08.31
申请号 CH19790009463 申请日期 1979.10.22
申请人 SANKYO CO. LTD. 发明人 YASUO YURA;ROKURO ENDO
分类号 B01J23/00;B01J27/00;B01J31/00;C07B61/00;C07C51/00;C07C51/15;C07C61/15;C07C61/40;C07C67/00;C07C69/63;C07C69/743;(IPC1-7):C07C61/35;C07C69/74 主分类号 B01J23/00
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