| 摘要 |
<p>2-Isocyanatosulfonylbenzoic acid esters of the general formula
<CHEM>
wherein R is selected from various hydrocarbyl and substituted hydrocarbyl groups;
R2 is H, Cl, Br, F, C1-C3 alkyl, -NO2, -OCH3, -SCH3, CF3, SO2CH3, N(CH3)2, CN, or 4-N=C=O; and
R3 is H, Cl, Br or CH3 with the proviso that when R is other than C3-C10 alkynyl, then R2 must be 4-NCO.
are novel intermediates for the preparation of herbicidal ureas. The isocyanates may be prepared e.g. by reacting a corresponding 2-sulfamoylbenzoate ester of general formula
<CHEM>
wherein R2 min is NH2 or R2 as defined above, with a hydrocarbyl isocyanate and phosgene in the presence of a catalytic amount of a tertiary amine base and an inert solvent. </p> |
