发明名称 Calcium ion-selective electrodes and membrane for use therein
摘要 A membrane for use in the determination of calcium ion concentration in an aqueous solution, the membrane being of the type comprising a calcium ion selective component and a carrier material. The membrane is characterized in that the calcium ion selective component is a compound having a formula (I) <IMAGE> (I) wherein X and Y are independently selected from the group consisting of aryl, alkyl(aryl), alkenyl(aryl), alkynyl(aryl), alkyl, cycloalkyl, alkenyl, cycloalkenyl, and alkynyl radicals wherein said alkyl moiety of said alkyl(aryl) radical consists of 1-12 carbon atoms; each alkenyl and alkynyl moiety of said alkenyl(aryl) and alkynyl(aryl) radicals, respectively, consists of 2-12 carbon atoms; each aryl moiety consists of 6, 10, 12, or 14 carbon atoms; and each alkyl, cycloalkyl, alkenyl, cycloalkenyl, and alkynyl radical consists of 6 to 14 carbon atoms; and Z is selected from a group consisting of alkyl radicals containing 1-12 carbon atoms; alkenyl and alkynyl radicals containing 4-12 carbon atoms; and cycloalkyl and cycloalkenyl radicals containing 6 to 12 carbom atoms. The membrane can be employed in an electrode system. A novel compound of formula I, supra, and a method for the manufacture thereof.
申请公布号 US4271002(A) 申请公布日期 1981.06.02
申请号 US19790107031 申请日期 1979.12.26
申请人 BECKMAN INSTRUMENTS, INC. 发明人 HAWKINS, JOHN J.
分类号 C07F9/12;C07F9/6533;G01N27/333;G01N27/414;(IPC1-7):G01N27/46 主分类号 C07F9/12
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