发明名称 |
ETHERS WHOSE ORGANIC MOIETIES HAVE ASYMMETRIC ATOMS, METHODS FOR THEIR PREPARATION AND THEIR USE FOR THE RESOLUTION OF ALCOHOLS, PHENOLS OR CERTAIN COMPOUNDS WITH A LACTONE STRUCTURE |
摘要 |
Novel ethers of organic compounds containing chiral atoms of the formula <IMAGE> I wherein A is a hydrocarbonated chain of 1 to 10 groups, the said chain containing one or more heteroatoms, one or more unsaturations, the assembly of the groups constituting the chain may represent a mono- or polycyclic system, including a system of the spiro or endo type, the chain A can contain one or more chiral atoms or the lactone moiety can present a chirality due to the dissymetric spatial configuration of the whole of the molecule and Z is selected from the group consisting of primary, secondary or tertiary alcohol moiety containing at least an asymetric carbon atom, a phenol moiety substituted comprising at least one asymetric carbon atom and an substituted alcohol or phenol moiety with a chirality due to the dissymetric spatial configuration of the whole of the molecule, with the proviso Z is not (R) or (S) alpha -cyano-3-phenoxy-benzyl when A is <IMAGE> which are useful for the resolution of compounds of the formulae <IMAGE> wherein A and Z have the above definitions and X is selected from the group consisting of hydrogen and alkyl of 1 to 4 carbon atoms. |
申请公布号 |
EP0004493(B1) |
申请公布日期 |
1981.05.06 |
申请号 |
EP19790400144 |
申请日期 |
1979.03.06 |
申请人 |
ROUSSEL-UCLAF |
发明人 |
MARTEL, JACQUES;TESSIER, JEAN;TECHE, ANDRE |
分类号 |
B01J31/02;C07B31/00;C07B57/00;C07B61/00;C07C27/00;C07C29/10;C07C29/88;C07C37/86;C07C41/18;C07C43/295;C07C45/57;C07C51/487;C07C62/02;C07C62/04;C07C67/00;C07D307/33;C07D307/88;C07D307/93;C07D315/00 |
主分类号 |
B01J31/02 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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