| 摘要 |
PURPOSE:To obtain a high-efficiency oxygen adsorbent/desorbent which contains the effective component of a combined substance of the macromolecule and the steric hindrance proximal basic iron porphyrin complex having only the steady 5- coordination structure. CONSTITUTION:This adsorbent/desorbent has the effective component of the steric hindrance proximal basic high molecular iron porphyrin complex which contains the unit of 40mol% in the formula, where A is the monomer unit obtained by combining the [-N(H)a] group with the main or side chain; (a) is 0 or 1; R<1> is H, vinyl group or ethyl group; and R<2> is H and methyl group and also has the number- average molucular weight of >=5,000 high molecular chain except the above-mentioned porphyrin complex part. For production of this component, both of the chained radicals to the C2CH4 in the formula changes one of the complexes of the -CO2H into the -CO2CH3 and then give a reaction to the another with the 2nd-class amino group in the form of a formula. Then the -CO2CH3 is turned into the -CO<2>H which is reacted withe the macromolucule shown by the poly-NH2. Thus the desired substance is obtained. |
